Reversibly-formed ion pairs are not involved during the solvolysis of N,O-diacetyl-N-arylhydroxylamines |
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| Authors: | Catherine M Scott Graham R Underwood Robert B Kirsch |
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| Institution: | Department of Chemistry, New York University, Washington Square, New York, New York, 10003 U.S.A. |
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| Abstract: | Appropriate oxygen-18 labeling experiments demonstrate that N,O-diarylhydroxylamines do not undergo solvolysis the reversible formation of ion pairs. This is in total conflict with the conclusions from previous indirect kinetic studies of these ultimate carcinogen models. |
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