Organometallic reactions of α-haloimines as a useful tool in organic synthesis |
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Authors: | Norbert de Kimpe Bart de Corte Roland Verhe Laurent de Buyck Niceas Schamp |
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Affiliation: | Laboratory of Organic Chemistry, Faculty of Agricultural Sciences, State University of Gent, Coupure 653, B-9000 Gent, Belgium |
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Abstract: | The reaction of organometallic reagents, e.g. alkyllithiums, cuprates and alkylcoppers, with α-haloimines gave selectively a variety of synthetically useful reactions, including coupling to 1,4-diimines, homologation, and production of heterocycles. |
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