A versatile route to silylsubstituted ketones by rhodium catalyzed isomerization of silylated allyl alcohols |
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| Authors: | Susumu Sato Hisashi Okada Isamu Matsuda Yusuke Izumi |
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| Institution: | Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University, Chikusa, Nagoya 464, JAPAN |
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| Abstract: | The rhodium catalyzed isomerization of α-, β-, and γ-silylated allyl alcohols has been successfully applied to the selective synthesis of acylsilane, α-silyl ketones, and β-silyl ketones, respectively. |
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