Direct reductive amination of carbonyl compounds with primary/secondary amines using recyclable water-soluble Fe/EDTA complex as catalyst |
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| Authors: | Malhari D Bhor |
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| Institution: | Department of Chemistry, Institute of Chemical Technology, University of Mumbai, N. Parekh Marg, Matunga, Mumbai 400019, India |
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| Abstract: | Direct reductive amination of aliphatic, aromatic and heterocyclic carbonyl compounds with primary/secondary amines is reported with water-soluble FeII/EDTA complex as a catalyst using low-pressure molecular hydrogen in a biphasic media. The catalyst is highly selective, recyclable and is an excellent replacement for expensive noble metal catalysts or stoichiometric reducing agents. |
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| Keywords: | Water-soluble catalyst Imines Hydrogenation Biphasic catalysis |
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