Thio-functionalised glucosinolates: unexpected transformation of desulfoglucoraphenin |
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| Authors: | Renato Iori,Estelle Gallienne,Arnaud Tatibouë t |
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| Affiliation: | a Consiglio per la Ricerca e la Sperimentazione in Agricoltura (C.R.A.-ISCI), I-40129 Bologna, Italy
b Institut de Chimie Organique et Analytique, Associé au CNRS, Université d’Orléans, B.P. 6759, F-45067 Orléans, France |
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| Abstract: | Enzymatic desulfation of stable glucoraphenin affords desulfoglucoraphenin, which unexpectedly undergoes further transformations into cyclic nitrone-type derivatives. |
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| Keywords: | Glucosinolates Desulfoglucosinolates Vinylthio functions Thioimidate N-oxides |
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