| Dicyano-Functionalized MCM-41-Supported Palladium Complex as An Efficient Catalyst for Allylation of Aldehydes and Ketones |
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| 作者姓名： | 赵红 蔡明中 |
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| 作者单位： | [1]Department of Chemistry, Jiangxi Normal University, Nanchang, Jiangxi 330027, China [2]Department of Pharmacy, Guangdong Pharmaceutical College, Guangzhou, Guangdong 510240, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （No. 20462002）. |
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| 摘 要： |
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| 关 键 词： | 烯丙基化 双氰功能化MCM-41 催化剂 异体钯催化 高烯丙醇 酮 醛 |
| 收稿时间： | 2006-02-06 |
| 修稿时间： | 2006-02-062006-06-08 |
Dicyano-Functionalized MCM-41-Supported Palladium Complex as An Efficient Catalyst for Allylation of Aldehydes and Ketones |
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| ZHAO, Hong, CAI, Ming-Zhong.Dicyano-Functionalized MCM-41-Supported Palladium Complex as An Efficient Catalyst for Allylation of Aldehydes and Ketones[J].Chinese Journal of Chemistry,2006,24(11):1669-1673. |
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| Authors: | ZHAO Hong CAI Ming-Zhong |
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| Institution: | a Department of Chemistry, Jiangxi Normal University, Nanchang, Jiangxi 330027, China; b Department of Pharmacy, Guangdong Pharmaceutical College, Guangzhou, Guangdong 510240, China |
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| Abstract: | Dicyano-functionalized MCM-41-supported palladium complex was prepared from dicyano-functionalized MCM-41 and palladium chloride. This complex exhibited high catalytic activity in the allylation of aldehydes and ketones with allylic chlorides in the presence of SnCl2. This polymeric palladium complex can be recovered and reused without noticeable loss of activity. |
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| Keywords: | allylation dicyano-functionalized MCM-41 heterogeneous palladium catalysis homoallylic alcohol |
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