Abstract: | The products of the reaction of 2-aryl-5-R-5,6-dihydro-7H-1,2,4]triazolo5,1-b]1,3]thiazin-7-ones with aryl bromomethyl ketones are 2-aryl-7H-1,2,4]triazolo5,1-b]1,3]thiazin-7-ones and aryl methyl ketones or 2,5-diaryl1,3]thiazolo3,2-b]1,2,4]triazoles and 3-phenyl-2-propenoic acid, depending on the structure of R. The reaction of 2-aryl-5-R-5,6-dihydro-7H-1,2,4]triazolo5,1-b]1,3]thiazin-7-ones with benzyl bromide yields 5-aryl-3-benzylthio-4H-1,2,4-triazoles and 3-aryl-2-propenoyl bromide.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 905–909, June, 2005. |