Synthesis,Structure and Selective Chlorination of Bis(N‐borane‐dimethylaminopropyl)telluride |
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| Authors: | Jens Beckmann Prof. Dr. Emanuel Fleige Nicolai Schnurbusch |
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| Affiliation: | 1. Berlin, Freie Universit?t, Institut für Chemie und BiochemieInstitut für Chemie und Biochemie, Freie Universit?t Berlin, Fabeckstra?e 34–36, D‐14195 Berlin, Tel. Int. code +49 (0)30‐838‐54697, Fax. Int. code +49 (0)30‐838‐52440;2. Berlin, Freie Universit?t, Institut für Chemie und Biochemie |
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| Abstract: | ![]()
The reaction of Te powder, NaBH4 and Me2N(CH2)3Cl·HCl provided the title compound [H3BNMe2(CH2)3]2Te ( 1 ), whose selective chlorination with SO2Cl2 lead to the formation of [ClH2BNMe2(CH2)3]2TeCl2 ( 2 ) and [Cl3BNMe2(CH2)3]2TeCl2 ( 3 ), respectively. Compounds 1 – 3 were characterized by multinuclear NMR spectroscopy and single crystal X‐ray diffraction. |
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| Keywords: | Tellurium Boron NMR spectroscopy Crystal structure |
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