UV‐photodimerization in uracil‐substituted dendrimers for high density data storage |
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| Authors: | Brian Lohse Robert Vestberg Mario T Ivanov Søren Hvilsted Rolf H Berg P S Ramanujam Craig J Hawker |
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| Institution: | 1. Polymer Department, Ris? National Laboratory, DK‐4000 Roskilde, Denmark;2. Department of Optics and Plasma Research, Ris? National Laboratory, DK‐4000 Roskilde, Denmark;3. Department of Chemistry and Materials and Materials Research Laboratory, University of California Santa Barbara, California‐93106;4. Danish Polymer Centre, Technical University of Denmark, DK‐2800 Kgs. Lyngby, Denmark;5. Department of Chemical Engineering, Technical University of Denmark, DK‐2800 Kgs. Lyngby, Denmark;6. Department of Chemistry and Materials and Materials Research Laboratory, University of California Santa Barbara, California‐93106Department of Chemistry and Materials and Materials Research Laboratory, University of California Santa Barbara, California‐93106 |
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| Abstract: | Two series of uracil‐functionalized dendritic macromolecules based on poly (amidoamine) PAMAM and 2,2‐bis(hydroxymethylpropionic acid) bis‐MPA backbones were prepared and their photoinduced (2π+2π) cycloaddition reactions upon exposure to UV light at 257 nm examined. Dendrimers up to 4th generation were synthesized and investigated as potential materials for high capacity optical data storage with their dimerization efficiency compared to uracil as a reference compound. This allows the impact of increasing the generation number of the dendrimers, both the number of chromophores, as well as the different steric environments, on the performance of each series of dendrimers to be investigated. The (uracil)12‐G‐2]‐bis‐MPA and (uracil)8‐G‐1]‐PAMAM were observed to have high dimerization efficiency in solution with different behavior being observed for the PAMAM and bis‐MPA dendrimers. The dendrimers with the best dimerization efficiency in solution were then examined in the solid state as thin films cast on quartz plates, and their film qualities along with their photodimerization performance studied. High quality films with a transmission response of up to 70% in 55 s. when irradiated at 257 nm with an intensity of 70 mW/cm2 could be obtained suggesting future use as recording media for optical data storage. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4401–4412, 2007 |
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| Keywords: | dendrimers functionalization of polymers photochemistry |
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