Synthesis and Crystal Structure of a Novel Polymeric Lead(II) Compound: [Pb2(phen)2(N3)3(ClO4)]n |
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| Authors: | Farzin Marandi Dr Babak Mirtamizdoust Suchada Chantrapromma Hoong‐Kun Fun |
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| Institution: | 1. Department of Science, Payam Noor University of Zanjan, Zanjan / IranDepartment of Science, Payam Noor University of Zanjan, Zanjan / Iran;2. Zanjan/Iran, Department of Chemistry, Zanjan University;3. Songkhla/Thailand, Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat‐Yai;4. Penang/Malaysia, X‐ray Crystallography Unit, School of Physics, Universiti Sains Malaysia |
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| Abstract: | A 2D lead(II) coordination polymer Pb2(phen)2(N3)3(ClO4)]n,( 1 ) containing 1,10‐phenanthroline (phen) and two different anions, has been synthesized and characterized by elemental analysis, IR and 1H NMR spectroscopy and X‐ray crystallography. The single‐crystal X‐ray data show two different kinds of Pb2+ ions with coordination numbers of eight, Pb1 = PbN6O2 and Pb2 = PbN8, with hemidirected and holodirected structures, respectively. The supramolecular features in 1 is negiotated through the weak but directional C‐H···O and C‐H···N interactions and aromatic π–π stacking interactions. |
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| Keywords: | Lead Azide Coordination polymer |
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