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The Structure of Tris(trifluoromethyl)tellurium Fluoride Dimethylformamide, $rm [Te(CF_{3})_{3} times DMF(mu-F)]{infty}$
Authors:Natalya V. Kirij  Yurii L. Yagupolskii  Wieland Tyrra Dr.  Ingo Pantenburg  Dieter Naumann Prof. Dr.
Affiliation:1. Kiev / Ukraine, Institute of Organic Chemistry of the National Academy of Sciences;2. K?ln / Germany, Institut für Anorganische Chemie der Universit?tInstitut für Anorganische Chemie, Universit?t zu K?ln, Greinstr. 6, D‐50939 K?ln, Fax: 0221‐4705196;3. K?ln / Germany, Institut für Anorganische Chemie der Universit?t
Abstract:
equation image represents the first structurally characterized example of a trifluoromethyl main group element compound with more than 8‐N (where N is the main group number) perfluoroalkyl groups and also the first fluoro(triorgano)tellurium derivative. Its polymeric nature is caused by asymmetric bridging fluorine atoms forming infinite chains.
Keywords:Tellurium  Trifluoromethyl  Crystal structure
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