Isothermal (vapour + liquid) equilibrium at several temperatures of (1-chlorobutane + 1-butanol,or 2-methyl-2-propanol) |
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| Affiliation: | 1. Center for Diabetes and Metabolic Diseases, Department of Internal Medicine, Melk, Austria;2. Division of Endocrinology and Metabolism, Department of Internal Medicine III, Medical University of Vienna, Vienna, Austria;1. Department of Metallurgical and Materials Engineering, National Institute of Technology, Tiruchirappalli, 620015, Tamil Nadu, India;2. Department of Physics, National Institute of Technology, Tiruchirappalli, 620015, Tamil Nadu, India;2. Pain & Neuroscience, Discovery Research Laboratories for Core Therapeutic Areas, Shionogi & Co., Ltd., 1-1 Futaba-cho, 3-chome, Toyonaka, Osaka 561-0825, Japan;3. Antibody Therapeutics, Discovery Research Laboratory for Innovative Frontier Medicines, Shionogi & Co., Ltd., 1-1 Futaba-cho, 3-chome, Toyonaka, Osaka 561-0825, Japan;4. Biomarker, Biotechnology-Based Medicine, Discovery Research Laboratory for Innovative Frontier Medicines, Shionogi & Co., Ltd., 1-1 Futaba-cho, 3-chome, Toyonaka, Osaka 561-0825, Japan;1. Department of Biological and Environmental Sciences, College of Arts and Sciences, Qatar University, Doha, P.O. Box: 2713, Qatar;2. Division of Sustainable Development, College of Science and Engineering, Hamad Bin Khalifa University, Doha, Qatar;1. Key Laboratory of Hunan Forest Products and Chemical Industry Engineering, College of Chemistry and Chemical Engineering, Jishou University, Zhangjiajie 427000, China;2. Institute of Bast Fiber Crops and Center of Southern Economic Crops, Chinese Academy of Agricultural Sciences, Changsha 410205, China;1. Department of Gynecology, Hôpital Femme Mère Enfant, 59 Boulevard Pinel, Hospices civils de Lyon, 69000 Lyon, France;2. Université Claude Bernard Lyon 1, EMR 3738, 69000 Lyon, France;3. Department of Gyncology, AGYL, 86 Avenue des Vosges, 67000 Strasbourg, France |
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| Abstract: | Vapour pressures of (1-chlorobutane + 1-butanol, or 2-methyl-2-propanol) at several temperatures between T = 278.15 and T = 323.15 K were measured by a static method. Reduction of the vapour pressures to obtain activity coefficients and excess molar Gibbs energies was carried out by fitting the vapour pressure data to the Redlich–Kister equation according to Barker’s method. For (1-chlorobutane + 2-methyl-2-propanol) azeotropic mixtures with a minimum boiling temperature were observed over the whole temperature range. |
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