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多组分金属催化剂表面漫反射紫外可见光谱研究
引用本文:唐波,江琦,何锡文,沈含熙.多组分金属催化剂表面漫反射紫外可见光谱研究[J].光谱学与光谱分析,1999,19(1):98-101.
作者姓名:唐波  江琦  何锡文  沈含熙
作者单位:1. 山东师范大学化学系,250014,济南
2. 南开大学化学系,300071,天津
基金项目:国家教委博士点基金,山东省青年自然科学基金
摘    要:研究了二氧化碳加氢甲烷化二组分、三组分担载型金属催化剂表面漫反射紫外可见光谱(DRUVS)。根据DRUVS提供的信息,揭示了催化剂组分间相互作用结果对催化活性的影响;不同助剂量催化剂DRUVS特征强度与催化活性间定量关系也得到合理确定 。

关 键 词:漫反射紫外可见光谱  二氧化碳加氢甲烷化  多组分催化剂

Study on the Surface Diffuse Reflectance Ultraviolet-Visible Spectra of the Multicomponent Metal Catalysts
Bo TANG,Qi JIANG,Xiwen HE,Hanxi SHEN.Study on the Surface Diffuse Reflectance Ultraviolet-Visible Spectra of the Multicomponent Metal Catalysts[J].Spectroscopy and Spectral Analysis,1999,19(1):98-101.
Authors:Bo TANG  Qi JIANG  Xiwen HE  Hanxi SHEN
Institution:Department of Chemistry, Shandong Normal University, 250014 Jinan.
Abstract:In this paper,the surface diffuse reflectance ultraviolet visible spectra(DRUVS)of two and three components supported metal catalysts for methanation of CO 2 by hydrogenation were studied, and the relationship between the activity of catalytic hydrogenation and the interaction among the components of the catalysts was revealed.Based on the analysis of the DRUVS of the catalysts with defferent amount of promoters in two component catalysts system,the dependence relationship between the characteristic strength of the DRUVS and the catalytic activity was worked out.
Keywords:Diffuse reflectance ultraviolet  visible spectrum    Methanation CO  2 by hydrogenation    Multicomponent catalyst  
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