Flory radius of polymers in a periodic field: An exact analytic theory

We found an exact expression for the Flory radius R _F of Gaussian polymers placed in an external periodic field. This solution is expressed in terms of the two parameters η and a that describe the reduced strength of an external field and the period of the field to the polymer gyration radius ratio, respectively. R _F is found to be a decaying function of η for any values of a . Provided that the gyration radius is of the order of the period of an external field or less, the ground-state (GS) approximation of the exact result for R _F is shown to give qualitatively incorrect results. In addition to the “ground-state” contribution, the exact solution for R _F contains an additional term that is overlooked by the GS approximation. This term gives rise to the fact that R _F as a function of η exhibits power law behavior (rather than exponential decay obtained from the GS result) once η exceeds the threshold value η_con .