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Regioselective Synthesis of 4‐(Arylsulfanyl)‐2‐hydroxyhomophthalates by [4+2] Cycloaddition of 3‐(Arylsulfanyl)‐1‐(trimethylsilyloxy)buta‐1,3‐dienes with Dimethyl Penta‐2,3‐dienedioate
Authors:Muhammad Imran  Inam Iqbal  Christine Fischer  Peter Langer
Affiliation:1. Institut für Chemie, Universit?t Rostock, Albert‐Einstein‐Str. 3a, D‐18059 Rostock, (fax: +49?381?4986412);2. Leibniz‐Institut für Katalyse e. V. an der Universit?t Rostock, Albert‐Einstein‐Str. 29a, D‐18059 Rostock
Abstract:The [4+2] cycloaddition of 3‐(arylsulfanyl)‐1‐(trimethylsilyloxy)buta‐1,3‐dienes with dimethyl penta‐2,3‐dienedioate provides a convenient and regioselective approach to a variety of 4‐(arylsulfanyl)‐2‐hydroxyhomophthalates.
Keywords:Allenes  Cycloadditions  Sulfur  Regioselectivity  Homophthalates, 4‐(arylsulfanyl)‐2‐hydroxy‐
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