A New Lycopodine Alkaloid from Phlegmariurus yunnanensis Ching |
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Authors: | Xiaoyan Xie Jinhe Jiang Ying Liu Kang Min Yongmei Xue Bi Jing Yan Zhang Yegao Chen |
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Institution: | 1. Department of Chemistry, Yunnan Normal University, Street 121, Kunming 650092, P.?R. China, (phone and fax: +86‐871‐5516061);2. Diqing Institute of Agricultural Science, Shangrila 674400, P.?R. China;3. Department of Chemistry, Kunming Medical College, West Reming Road, Kunming 650092, P.?R. China |
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Abstract: | A new lycopodine alkaloid, 15α‐methyllycopodane‐5β,6β‐diol N‐oxide ( 1 ), was isolated from the whole plants of Phlegmariurus yunnanensis Ching , together with the two known alkaloids 15α‐methyllycopodane‐5β,6β‐diol ( 2 ) and lycoposerramine H ( 3 ), and four serratene‐type triterpenoids, serratenediol‐3‐acetate ( 4 ), serratenediol ( 5 ), lycocryptol ( 6 ), and serratriol ( 7 ). Their structures were elucidated on the basis of spectroscopic analyses, including HR‐ESI‐MS, 1H‐ and 13C‐NMR, DEPT, 1H,1H‐COSY, HSQC, HMBC, and NOESY. |
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Keywords: | Phlegmariurus yunnanensis Alkaloids Lycopodine alkaloids Triterpenes Serratene‐type triterpenoids |
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