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Non-adiabatic quantum molecular dynamics: General formalism and case study H2+ in strong laser fields
Authors:T.?Kunert  author-information"  >  author-information__contact u-icon-before"  >  mailto:kunert@physik.tu-dresden.de"   title="  kunert@physik.tu-dresden.de"   itemprop="  email"   data-track="  click"   data-track-action="  Email author"   data-track-label="  "  >Email author,R.?Schmidt
Affiliation:(1) V.A. Fock Institute of Physics, The University of St Petersburg, 198904 St Petersburg, Russia, RU;(2) Institute of Physics and Astronomy, Aarhus University, 8000 Aarhus C, Denmark, DK
Abstract:In Rydberg atoms subject to static and harmonic collinear electric fields, intrashell transition can be induced by the first order perturbation from a small perpendicular electric or magnetic field, or by effects of the second order in the major fields. Both mechanisms lead to resonances that are suppressed under certain conditions, and high-frequency interference oscillations in case of non-adiabatic field switching. Recent measurements of microwave ionization signals show very rich and fascinating structures similar to the ones predicted for intrashell mixing. We show that the observed ionization structures may be explained by diabatic electric-field ionization and the consistent use of perturbation theory for intrashell mixing. In particular, the dominant oscillation frequency is successfully interpreted in terms of interference between first and second order transition amplitudes. New predictions are provided. The present approach gives a comprehensive picture of intrashell transitions, which may be tested in future experiments designed to observe such transitions directly. Received 2 May 2002 / Received in final form 23 September 2002 Published online 21 January 2003 RID="a" ID="a"e-mail: Valentin.Ostrovsky@pobox.spbu.ru RID="b" ID="b"e-mail: horsdal@ifa.au.dk
Keywords:PACS. 32.80.Rm Multiphoton ionization and excitation to highly excited states (e.g. Rydberg states) –   42.50.Hz Strong-field excitation of optical transitions in quantum systems   multiphoton processes   dynamic Stark shift
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