A Symmetry-Broken Charge-Separated State in the Marcus Inverted Region |
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Authors: | Ebin Sebastian Mahesh Hariharan |
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Institution: | School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram (IISER TVM), Maruthamala P.O., Vithura, Thiruvananthapuram, 695551 Kerala, India |
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Abstract: | We report a long-lived charge-separated state in a chromophoric pair ( DC-PDI2 ) that uniquely integrates the advantages of fundamental processes of photosynthetic reaction centers: i) Symmetry-breaking charge-separation (SB-CS) and ii) Marcus-inverted-region dependence. The near-orthogonal bichromophoric DC-PDI2 manifests an ultrafast evolution of the SB-CS state with a time constant of =0.35±0.02 ps and a slow charge recombination (CR) kinetics with =4.09±0.01 ns in ACN. The rate constant of CR of DC-PDI2 is 11 686 times slower than SB-CS in ACN, as the CR of the PDI radical ion-pair occurs in the deep inverted region of the Marcus parabola ( >λ). In contrast, an analogous benzyloxy (BnO)-substituted DC-BPDI2 showcases a ≈10-fold accelerated CR kinetics with lowering to ≈1536 in ACN, by virtue of a decreased CR driving force. The present investigation demonstrates a control of molecular engineering to tune the energetics and kinetics of the SB-CS material, which is essential for next-generation optoelectronic devices. |
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Keywords: | Bichromophores Charge-Transfer Coupling Excitons Perylenediimides Ultrafast Dynamics |
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