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Zeeman effect and stark splitting of the electronic states of the rare-earth ion in the paramagnetic terbium garnets Tb3Ga5O12 and Tb3Al5O12
Authors:U. V. Valiev  J. B. Gruber  D. K. Sardar  B. Zandi  I. S. Kachur  A. K. Mukhammadiev  V. G. Piryatinskaya  V. Yu. Sokolov  I. S. Edelman
Affiliation:(1) National University of Uzbekistan, Tashkent, 700174, Uzbekistan;(2) University of Texas at San Antonio, San Antonio, Texas 78249-0697, USA;(3) ARL/Adelphi Laboratory Center, Adelphi, Maryland 20783-1197, USA;(4) Verkin Institute for Low Temperature Physics and Engineering, National Academy of Sciences of Ukraine, pr. Lenina 47, Kharkov, 61103, Ukraine;(5) Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russia
Abstract:
The Zeeman effect in the 7 F 65 D 4 absorption band of the Tb3+ ion in the paramagnetic garnets Tb3Ga5O12 and Tb3Al5O12 was studied. The field dependences of the Zeeman splitting of some absorption lines are found to exhibit unusual behavior: as the magnetic field increases, the band splitting decreases rather than increases. Symmetry analysis relates these lines to 4f → 4f electron transitions of the doublet-quasi-doublet or quasi-doublet-doublet type, for which the field dependences of the splitting differ radically from the well-known field dependences of the Zeeman splitting for quasi-doublet-quasi-doublet or quasi-doublet-singlet transitions in a longitudinal magnetic field.
Keywords:
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