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Circular dichroism spectra of the inclusion complexes of phlorizin in cyclodextrins
Authors:Yasuko Ishizuka  Yoshinobu Nagawa  Hiroshi Nakanishi  Akira Kuboyama
Institution:(1) National Chemical Laboratory for Industry, Tsukuba Research Center, Ibaraki, Japan
Abstract:Two aromatic rings of a phlorizin molecule form inclusion complexes with beta-CD and gamma-CD. Induced circular dichroism spectra of these complexes have been measured to estimate the orientation of the two aromatic rings in the hydrophobic space of CDs. Apparent complex formation constants have been also estimated for each complex. It is concluded that phlorizin forms a stronger inclusion complex with beta-CD than with gamma-CD.
Keywords:Cyclodextrin  inclusion complex  phlorizin  circular dichroism
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