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| 氧气为唯一氧化剂的交叉脱氢偶联反应研究进展 | |
| 引用本文： | 庄伟辉,张晓凤,黄秋锋. 氧气为唯一氧化剂的交叉脱氢偶联反应研究进展[J]. 有机化学, 2021, 0(2): 529-542 |
| 作者姓名： | 庄伟辉 张晓凤 黄秋锋 |
| 作者单位： | 福建师范大学化学与材料学院;福建省高分子材料重点实验室 |
| 基金项目： | 国家自然科学基金(No.21872028);福建省教育厅青年重点基金(No.JZ160424);福建省高校新世纪人才基金资助项目。 |
| 摘 要： | 脱氢偶联反应是最有效、最直接的构建C—C键或C—杂键的一种方法.但是目前大多数脱氢偶联反应需要使用化学计量的有毒氧化剂,如PhI(OAc)2、苯醌、Cu(Ⅱ)盐、有机过氧酸或hg(Ⅰ)盐等.氧气廉价易得,作为脱氢偶联反应中的唯一氧化剂,副产物只有水,不会产生其他有毒副产物,是绿色环境友好的方法.根据催化剂的分类,综述了... |
| 关 键 词： | 交叉脱氢偶联 氧气 唯一氧化剂 |
Recent Advances in Cross-Dehydrogenative-Coupling Reactions Using Molecular Oxygen as the Sole Oxidant |
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| Zhuang Weihui,Zhang Xiaofeng,Huang Qiufeng. Recent Advances in Cross-Dehydrogenative-Coupling Reactions Using Molecular Oxygen as the Sole Oxidant[J]. Chinese Journal of Organic Chemistry, 2021, 0(2): 529-542 | |
| Authors: | Zhuang Weihui Zhang Xiaofeng Huang Qiufeng |
| Affiliation: | (College of Chemistry&Materials Science,Fujian Normal University,Fuzhou 350007;Key Laboratory of Polymer Materials of Fujian Province,Fuzhou 350007) |
| Abstract: | Cross-dehydrogenative-coupling(CDC) reactions have emerged as one of the most efficient and straightforward methods for the formation of C-C bonds or C-heteroatom bonds. However, most CDC reactions require hazardous and stoichiometric oxidants, such as PhI(OAc)2, benzoquinone, copper(Ⅱ) salts, organic peroxide acid and silver(Ⅰ) salts. A green and environmentary benign approach is using molecular oxygen(O2) as oxidant in the reactions, which usually form water as by-product. According to the classification of catalysts, the research progress of cross dehydrogenation coupling reaction with oxygen as the only oxidant is reviewed. |
| Keywords: | cross-dehydrogenative-coupling molecular oxygen oxidant |
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