| 一氟甲基二硫化物的高效合成 |
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| 引用本文： | 胡晓光,庞仁艺,郑天骄,姚瑞超,陈文博.一氟甲基二硫化物的高效合成[J].有机化学,2021(3):1117-1123. |
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| 作者姓名： | 胡晓光 庞仁艺 郑天骄 姚瑞超 陈文博 |
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| 作者单位： | 上海电力大学环境与化学工程学院上海市电力材料防护与新材料重点实验室;中国科学院上海有机化学研究所中科院能量调控材料重点实验室 |
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| 基金项目： | 上海市自然科学基金(No.20ZR1471600);上海市科学技术委员会(No.19DZ2271100);中国科学院能量调控材料重点实验室开放基金(No.ORFP2020-06)资助项目。 |
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| 摘 要： | 以PhSO2SCH2F为一氟甲硫基化试剂,室温下实现了硫酚/硫醇的一氟甲硫基化反应,高收率地合成了一系列一氟甲基二硫化物.该方法具有反应时间短、条件温和、操作简单以及无需外加添加剂等特点,为高效制备一氟甲基二硫化物提供了一条简便的途径.
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| 关 键 词： | 一氟甲硫基 二硫化物 PhSO2SCH2F 硫酚 |
High Efficient Synthesis of Monofluoromethyldisulfides |
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| Xiaoguang Hu,Renyi Pang,Tianjiao Zheng,Ruichao Yao,Wenbo Chen.High Efficient Synthesis of Monofluoromethyldisulfides[J].Chinese Journal of Organic Chemistry,2021(3):1117-1123. |
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| Authors: | Xiaoguang Hu Renyi Pang Tianjiao Zheng Ruichao Yao Wenbo Chen |
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| Institution: | (Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power,College of Environmental and Chemical Engineering,Shanghai University of Electric Power,Shanghai 200090;CAS Key Laboratory of Energy Regulation Materials,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032) |
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| Abstract: | The monofluoromethylthiolation reaction of thiophenols/mercaptans was developed at room temperature using PhSO2SCH2F as monofluoromethylthiolation reagent,and a series of monofluoromethyl disulfides were synthesized in good yields.This method features short reaction time,mild conditions,simple operation and no additives.It provides a simple and convenient way for the efficient preparation of monofluoromethyl disulfides. |
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| Keywords: | monofluoromethylthio disulfide PhSO2SCH2F thiophenol |
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