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Palladium complexes bearing an N‐heterocyclic carbene–sulfonamide ligand for cooligomerization of ethylene and polar monomers
Authors:Wenjie Tao  Xiaoming Wang  Shingo Ito  Kyoko Nozaki
Abstract:Herein, we report the synthesis of palladium complexes bearing an N‐heterocyclic carbene (NHC)‐sulfonamide bidentate ligand and their application in ethylene oligomerization and ethylene/polar monomer cooligomerization. These catalysts could smoothly catalyze ethylene oligomerization and ethylene/methyl acrylate cooligomerization albeit the performance was lower compared to that of a NHC–phenoxide catalyst. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 474–477
Keywords:catalysis  cooligomerization  ethylene  functionalization of polymers  N‐heterocyclic carbene  polar monomer  polyolefins  sulfonamide
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