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| Hydrothermal Synthesis and Crystal Structure of [H_4As_8V_(14)O_(42)(H_2O)]·6H_2O | |
| 引用本文： | CUI Xiao-Binga,b XU Ji-Qingb LI Guang-Huab SHI Zhanb DING Hongb YANG Guo-Yua,c② a(State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China) b(College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,Jilin University,Changchun 130023,China) c(State Key Laboratory of Coordination Chemistry,Nanjing University,Jiangsu 210093,China). Hydrothermal Synthesis and Crystal Structure of [H_4As_8V_(14)O_(42)(H_2O)]·6H_2O[J]. 结构化学, 2004, 0(10) |
| 作者姓名： | CUI Xiao-Binga b XU Ji-Qingb LI Guang-Huab SHI Zhanb DING Hongb YANG Guo-Yua c② a(State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China) b(College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry Jilin University Changchun 130023 China) c(State Key Laboratory of Coordination Chemistry Nanjing University Jiangsu 210093 China) |
| 作者单位： | CUI Xiao-Binga，b XU Ji-Qingb LI Guang-Huab SHI Zhanb DING Hongb YANG Guo-Yua，c② a(State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China) b(College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry，Jilin University，Changchun 130023，China) c(State Key Laboratory of Coordination Chemistry，Nanjing University，Jiangsu 210093，China) |
| 基金项目： | Supported by the National NSF of China (No. 20271050 20271021 and 20333070) and the NSF of Fujian province (No.210029) |
| 摘 要： | 1 INTRODUCTION The chemistry of polyoxometalates continues to attract interest as a result of their realized and potential applications in diverse fields, such as cata- lysis, analysis, biochemistry, medicine and material science[1～3]. In the past few … |
Hydrothermal Synthesis and Crystal Structure of [H_4As_8V_(14)O_(42)(H_2O)]·6H_2O |
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| Abstract: | The title compound [H4As8V14O42(H2O)]6H2O 1 has been synthesized and characterized by elemental analysis, IR, and single-crystal X-ray diffraction analysis. It crystallizes in trigonal, space group R3c with a = b = 36.447(6), c = 21.485(5) ? V = 24717(8) 3, Z = 18, Mr = 2114.66, Dc = 2.557g/cm3, F(000) = 17928, m = 7.149 mm-1, R = 0.0792 and wR = 0.1265. The [H4As8V14O42- (H2O)] cluster consists of fourteen VO5 square pyramids linked by four As2O5 handle-like units. |
| Keywords: | hydrothermal synthesis polyoxometalate arsenic-vanadium cluster hydrogen bond crystal structure |
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