| 金属配合物催化氮杂环丙烷化和饱和C-H键氮插入反应 |
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| 引用本文： | 王钦,李玫,余孝其,谢如刚.金属配合物催化氮杂环丙烷化和饱和C-H键氮插入反应[J].化学进展,2005,17(2):0-285. |
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| 作者姓名： | 王钦 李玫 余孝其 谢如刚 |
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| 作者单位： | 四川大学化学学院,成都,610064;泸州医学院,泸州,646000;四川大学化学学院,成都,610064 |
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| 基金项目： | 国家自然科学基金 (No .2 0 2 72 0 39)，教育部留学回国人员基金资助 |
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| 摘 要： | 氮杂环丙烷是有机合成之砌块,其合成方法是重要的研究课题.本文全面介绍了近20年来的氮杂环丙烷的金属配合物催化合成,尤其是以氮宾转移到烯烃或碳宾加成到亚胺 为合成途径的氮杂环丙烷化催化反应的研究进展,还包括该反应在金属催化时发生的竞争性插入到饱和C-H键的反应.
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| 关 键 词： | 氮杂环丙烷化 氮宾 碳宾 插入反应 |
| 文章编号： | 1005-281X(2005)02-0275-11 |
| 收稿时间： | 2003-12-01 |
| 修稿时间： | 2003年12月1日 |
Progress in Catalytic Aziridination of Alkenes and the Metal-Catalyzed Insertions into Saturated C-H Bonds |
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| Wang Qin,Li Mei,Yu Xiaoqi,Xie Rugang.Progress in Catalytic Aziridination of Alkenes and the Metal-Catalyzed Insertions into Saturated C-H Bonds[J].Progress in Chemistry,2005,17(2):0-285. |
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| Authors: | Wang Qin Li Mei Yu Xiaoqi Xie Rugang |
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| Institution: | 1.Department of Chemistry, Sichuan University,Chengdu 610064,China;
2.Luzhou Medical College, Luzhou 64600,China |
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| Abstract: | Aziridines are useful building blocks for organic synthesis, which makes them attractive synthetic tai in their crwn right. This review focuses on aziridine synthesis catalyzed by metal complex during the last twenty years, pecially the jar-ogress of the catalytic aziridinations based on nitrene transfer to olefins or on carbene addition to imii The insertions into saturated C-H bonds, which may compete with metal-catalyzed aziridination, are also included. |
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| Keywords: | aziridination nitrene carbene insertions |
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