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Viscosity of liquid suspensions with fractal aggregates: Magnetic nanoparticles in petroleum colloidal structures
Authors:VI Lesin  Yu A Koksharov  GB Khomutov
Institution:a Oil&Gas Scientific Research Institute of RAS, Moscow, Russian Federation
b Institute of Crystallography of RAS, Moscow, Russian Federation
c Faculty of Physics, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
d Institute of General and Inorganic Chemistry RAS, Moscow, Russian Federation
Abstract:New physical model is presented resulting in a simple formula for the dependence of viscosity η of colloidal liquid solution on the shear rate G applicable to a wide variety of systems including complex natural liquids like petroleum. The principal point of the model is the fractal nature of colloid particle aggregates present in the liquid. Such aggregates are experimentally detected now in non-Newtonian liquids. The model is based on calculation of energy loss on colloidal particle aggregate of fractal structure localized in the flow of liquid with shear rate. We have performed the viscosity measurement experiments which confirmed successfully the developed physical model. Also, we demonstrate experimentally that petroleum colloidal particles and magnetic iron oxide nanoparticles can form composite fractal-like aggregates in natural petroleum materials. Our model can explain both the non-Newtonian properties of petroleum and sensitivity of petroleum viscosity to external magnetic fields.
Keywords:Theory  Viscosity  Colloidal solution  Magnetic particles  Shear rate  Petroleum
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