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A New Approach to Inducing Silicon Tethered Ring-closing Metathesis Reactions |
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| Authors: | YANG Hong-li VAULTIER Michel |
| Institution: | Synthèse et Electrosynthèse Organiques, UMR CNRS 6510, Université de Rennes 1, Campus de Beaulieu, Avenue du Général Leclerc, 35042 RENNES CEDEX, France |
| Abstract: | Ring-closing metathesis reactions involving diallyldiphenylsilane and diallyloxydiphenylsilane were successfully performed by using only 0 01 mol or even less of Grubbs' catalyst 1. The effects of reaction parameters, such as solvents, temperature and concentration of the catalyst are discussed. |
| Keywords: | Ring-closing metathesis reaction Grubbs' catalyst Diallyldiphenylsilane Diallyloxydiphenyl-silane |
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