Synthesis of 12-deoxyroyleanone, cryptoquinone, 11,14-dihydroxy-8,11,13-abietatrien-7-one, and related derivatives from dehydroabietic acid |
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| Authors: | Yoh-ichi Matsushita Yoshihisa Iwakiri Satoru Yoshida Kazuhiro Sugamoto Takanao Matsui |
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| Institution: | Faculty of Engineering, University of Miyazaki, Gakuen-Kibanadai, Miyazaki 889-2192, Japan |
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| Abstract: | Naturally occurring abietane quinones and hydroquinone, namely, 12-deoxyroyleanone (1a), cryptoquinone (4a), and 11,14-dihydroxyabieta-8,11,13-trien-7-one (5a), together with the epimers of tryptoquinones D (2) and F (3), were first synthesized from dehydroabietic acid (6). |
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| Keywords: | Synthesis Dehydroabietic acid 12-Deoxyroyleanone Cryptoquinone 11 14-Dihydroxyabieta-8 11 13-trien-7-one |
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