TEMPO-catalyzed oxidation of benzylic alcohols to aldehydes with the H2O2/HBr/ionic liquid [bmim]PF6 system |
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| Authors: | Nan Jiang |
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| Affiliation: | School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332, United States |
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| Abstract: | A selective oxidation of benzylic alcohols to the corresponding aldehydes in room temperature ionic liquid was achieved by using TEMPO/HBr/H2O2 system, and both ether-insoluble acetamido-TEMPO and ionic liquid [bmim]PF6 can be successfully recovered and reused for the oxidation of the same (different) substrate. |
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| Keywords: | TEMPO Alcohol oxidation Benzylic alcohols Ionic liquids [bmim]PF6 |
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