Synthesis,characterization and crystal structure of a 2D Cd(II) complex with a 4,4'‐diazenediyldiphthalic acid ligand |
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Authors: | Lu Lu Jun Wang Jian‐Wei Bai Yang Hou Bin Yang Bao‐Zhong Zhao |
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Abstract: | An exploration of the cadmium‐L system under hydrothermal condition, has led to the isolation of a novel framework {Cd(L)0.5(H2O)3]}n ( 1 ) (H4L = 4,4'‐diazenediyldiphthalic acid). Single‐crystal X‐ray analysis reveals that it crystallizes in the triclinic space group P‐1. a = 5.746(3) Å, b =6.526(4) Å, c = 14.701(8) Å, α=92.348(8), β = 99.622(6), γ=106.877(7)°. The CdII ions are linked into an extended 2‐D rectangle‐like structure via L ligands, which exhibits an attractive three‐connected honeycomb topological network. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) |
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Keywords: | Cd complex crystal structure topology |
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