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Thermodynamic properties of ternary systems: Calculation of standard enthalpies of solvation of triols, diols, and a series of their ethers in water-methanol mixed solvent
Authors:V. P. Korolev
Affiliation:(1) Institute of Chemistry of Solutions, Russian Academy of Sciences, Ivanovo, Russia
Abstract:An equation for the standard enthalpy of solvation of a compound in a binary solvent is derived. The enthalpies of solvation in water-methanol mixtures are estimated for 1,3-propane-and 1,6-hexanediols, 1,2,4-butane-and 1,3,5-pentanetriols, 2-methoxy-and 2-propoxyethanols, and diethylene glycol. The enthalpy of solvation of 1,2-dimethoxyethane in the water-methanol mixed solvent is determined experimentally.
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