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Heterogeneous continuous flow synthetic system using cyclohexane-based multiphase electrolyte solutions
Authors:Yohei OkadaTomohiko Yoshioka  Mikio KoikeKazuhiro Chiba
Affiliation:Department of Applied Life Science, Tokyo University of Agriculture and Technology, 3-5-8 Saiwai-cho, Fuchu, Tokyo 183-8509, Japan
Abstract:
The discovery that supporting electrolytes can be effectively confined in typical organic solvents in a c-Hex-based multiphase electrolyte solution has led to the development of a novel heterogeneous continuous flow synthetic system. PTFE fiber functions as a separation filter that can efficiently isolate the c-Hex phase from multiphase electrolyte solutions. This system has demonstrated both electrochemical solvating and carbon-carbon bond forming reactions. Hydrophobic substrates can be introduced into the reactor as c-Hex solutions, which are then electrochemically transformed into the target hydrophobic products that pass through the PTFE fiber as c-Hex solutions.
Keywords:Heterogeneous   Flow synthetic system   Cyclohexane   Multiphase electrolyte solution   PTFE fiber
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