Heterogeneous continuous flow synthetic system using cyclohexane-based multiphase electrolyte solutions |
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Authors: | Yohei OkadaTomohiko Yoshioka Mikio KoikeKazuhiro Chiba |
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Affiliation: | Department of Applied Life Science, Tokyo University of Agriculture and Technology, 3-5-8 Saiwai-cho, Fuchu, Tokyo 183-8509, Japan |
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Abstract: | The discovery that supporting electrolytes can be effectively confined in typical organic solvents in a c-Hex-based multiphase electrolyte solution has led to the development of a novel heterogeneous continuous flow synthetic system. PTFE fiber functions as a separation filter that can efficiently isolate the c-Hex phase from multiphase electrolyte solutions. This system has demonstrated both electrochemical solvating and carbon-carbon bond forming reactions. Hydrophobic substrates can be introduced into the reactor as c-Hex solutions, which are then electrochemically transformed into the target hydrophobic products that pass through the PTFE fiber as c-Hex solutions. |
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Keywords: | Heterogeneous Flow synthetic system Cyclohexane Multiphase electrolyte solution PTFE fiber |
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