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Isokinetic Relationships in Alcohol Oxidation with Chromic Acid
Authors:Paul Müller  Jean-Claude Perlberger
Abstract:The activation parameters for the oxidation of 13 secondary alcohols with chromic acid have been determined. Application of a statistical treatment of Exner 9] shows that the reactions are isoentropic with an average entropy of activation (ΔS) of ?24.0 e. u.
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