| 镧系离子(Nd3+,Ho3+,Er3+)同1-苯基-3-甲基-4-二氯乙酰基吡唑酮-5和二安替吡啉甲烷三元配合物的制备和超灵敏跃迁的研究 |
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| 引用本文： | 钱博,张进胜,赵忠顺,李聚源.镧系离子(Nd3+,Ho3+,Er3+)同1-苯基-3-甲基-4-二氯乙酰基吡唑酮-5和二安替吡啉甲烷三元配合物的制备和超灵敏跃迁的研究[J].无机化学学报,1989,5(1):59-67. |
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| 作者姓名： | 钱博 张进胜 赵忠顺 李聚源 |
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| 作者单位： | 陕西师范大学化学系, 西安,陕西师范大学化学系, 西安,陕西师范大学化学系, 西安,中国人民武装警察部队技术学院, 西安 |
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| 摘 要： | 对Ln3+(Nd3+,Ho3+,Er3+)-1-苯基-3-甲基-4-二氯乙酰基毗唑酮-5(HPMDCP)-二安替吡啉甲垸(DAM)体系乙醇,水溶液的分光光度法研究及对固态钕配合物的元素分析证实:三元配合物的组分比为Ln3+:HPMDCP:DAM=1:3:1,研究了钕的配合物的红外吸收光谱和热稳定性;计算了相应配合物的超灵敏跃迁的振子强度,并讨论了振于强度的增值与配体数目的关系及振子强度间的线性关系。
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| 关 键 词： | 镧系离子 三元配合物 HPMDCP DAM |
| 收稿时间： | 1987/8/11 0:00:00 |
STUDIES ON PREPARATION AND HYPERSENSITIVE TRANSITION FOR TERNARY COORDINATION COM-POUNDS OF LANTHANIDE FOR IONS (Nd3+ ,Ho3+ ,Er3+) WITH 1-PHENYL-3-METHYL-4-DICHLOROACETYL-PYRAZOLONE-5 AND DIANTIPYRYL METHANE |
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| Qian Bo,Zhang Jingsheng,Zhao Zhongshun and Li Juyuan.STUDIES ON PREPARATION AND HYPERSENSITIVE TRANSITION FOR TERNARY COORDINATION COM-POUNDS OF LANTHANIDE FOR IONS (Nd3+ ,Ho3+ ,Er3+) WITH 1-PHENYL-3-METHYL-4-DICHLOROACETYL-PYRAZOLONE-5 AND DIANTIPYRYL METHANE[J].Chinese Journal of Inorganic Chemistry,1989,5(1):59-67. |
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| Authors: | Qian Bo Zhang Jingsheng Zhao Zhongshun and Li Juyuan |
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| Institution: | Department of chemistry, Shanxi Normal University, Xian,Department of chemistry, Shanxi Normal University, Xian,Department of chemistry, Shanxi Normal University, Xian and The Technical Institute of the Chinese People's Armed Police Force, Xian |
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| Abstract: | |
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| Keywords: | ncodymium coordination compound holmium coordination compound crbiumcoordination compound 1-phenyl-3-methyl-4-dichloroacctyl-pyrazolone-5 diantipyryl methane |
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