CCC-N-heterocyclic carbene pincer complexes: Synthesis, characterization and hydroamination activity of a hafnium complex |
| |
| Authors: | Joon Cho Edward J Valente |
| |
| Institution: | a Department of Chemistry and Biochemistry, The University of Mississippi, 407 Coulter Hall, University, MS 38677, USAb Department of Chemistry, University of Portland Diffraction Facility, 112A Swindells Hall, University of Portland, Portland, OR 97203, USA |
| |
| Abstract: | Our methodology for the stoichiometric preparation of CCC-NHC pincer complexes of Zr has been extended to Hf. The CCCBu-NHC pincer Hf complex has been characterized by X-ray crystal structure analysis. Catalytic activity in the intramolecular hydroamination/cyclization of unactivated alkenes is reported and compared to the recently reported Zr analog. An improved, scaled-up CuO-catalyzed aryl amination of 1,3-dibromobenzene and an improved salt formation methodology for preparation of bis(butyl-imidazolium)benzene are reported also. |
| |
| Keywords: | Homogeneous catalysis N-Heterocyclic carbene Pincer complex Hydroamination Pyrrolidines Piperidines |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
