Hydrosilylation reactions catalyzed by rhodium complexes with phosphine ligands functionalized with imidazolium salts |
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| Authors: | Jiayun Li Guoqiao Lai |
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| Affiliation: | Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 310012, People’s Republic of China |
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| Abstract: | Hydrosilylation reactions of styrene with triethoxysilane catalyzed by rhodium complexes with phosphine ligands functionalized with imidazolium salts are reported. In comparison with Wilkinson’s catalyst, Rh(PPh3)3Cl, all of the present rhodium complexes with phosphines functionalized with imidazolium salts exhibit higher catalytic activity and selectivity. |
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| Keywords: | Hydrosilylation Catalyst Phosphines functionalized with imidazolium salts Rhodium complexes |
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