Cycloadditions of nonstabilized 2-azaallyllithiums with cycloheptatriene |
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| Authors: | Pearson William H Mans Douglas M Kampf Jeff W |
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| Affiliation: | Department of Chemistry, University of Michigan, Ann Arbor 48109-1055, USA. wpearson@umich.edu |
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| Abstract: | ![]()
[reaction: see text] Transmetalation of tin-bearing cyclic imidates gave 2-azaallyllithiums that underwent [pi6s + pi4s] cycloadditions with cycloheptatriene to produce tricyclic adducts, which may be useful as analogs of cocaine. The peri- and stereoselectivity of this process are discussed. |
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