Crystal structure of (diphenyl)(morpholino)phosphiniminocyclotrithiazene |
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| Authors: | J Srinivas G Sreenivasa Murthy C J Thomas M N Sudheendra Rao |
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| Institution: | (1) Department of Physics, Indian Institute of Technology, 600 036 Madras, India;(2) Department of Chemistry, Indian Institute of Technology, 600 036 Madras, India |
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| Abstract: | The title compound (C6H5)2(OC4H8N)P=N–S3N3 crystallizes in the space group
with unit cell parametersa=9.3900(2),b=9.4747(1),c=11.3850(3) Å,  =95.73(4),  =96.85(6),  =104.26(2)o, and Z=2. The tricoordinated sulfur of the cyclotrithiazene ring deviates from the mean plane of other skeletal atoms by 0.683(4) Å. The angle at this atom is the smallest in the ring and is enclosed by the longest S–N bonds observed in the ring. |
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| Keywords: | Cyclotrithiazene arylaminophospine crystal structure |
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