155Gd Mössbauer spectroscopy measurements on Gd2T17C
x,with T=Fe,Co, Ni andx varying from 0.6 to 1.2 |
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Authors: | M W Dirken R C Thiel T H Jacobs K H J Buschow |
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Institution: | (1) Kamerlingh Onnes Laboratorium, Leiden University, P.O. Box 9506, 2300 RA Leiden, The Netherlands;(2) Philips Research Laboratories, P.O. Box 8000, 5600 JA Eindhoven, The Netherlands |
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Abstract: | 155Gd Mössbauer measurements were performed on Gd2T17C x with T=Fe, Co, and Ni andx varying from 0.6 to 1.2. The crystal structures of these compounds are either the Th2Zn17 or the Th2Ni17 structure type. There is only partial occupation of the site available to the carbon atoms, leading to several crystallographically non-equivalent gadolinium surroundings. These various Gd sites show different quadrupole interactions. Doping with carbon causes an increased Curie temperature for the Gd2Fe17C x compounds. The randomness of the occupation by carbon has been studied. |
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