| 新型氮功能化大环配体的合成与表征 |
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| 引用本文： | 王世范.新型氮功能化大环配体的合成与表征[J].合成化学,2001,9(3):223-226. |
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| 作者姓名： | 王世范 |
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| 作者单位： | 华东冶金学院化学工程系,安徽,马鞍山,243002 |
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| 基金项目： | Supported by the National Natural Science Foundation of China(2 93 71 0 0 1 ) |
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| 摘 要： | 合成了新型氮功能化大环配体内消旋-5,5,7,12,12,14-六甲基-1,4,8,11-四氮杂环十四烷-N,N＇-二乙酸乙酯(TETADE);内消旋-5,5,7,12,12,14-六甲基-1,4,8,11-四氮杂环十四烷-N,N＇,N＇,N＇＇,N＇＇＇-四乙酸乙酯(TETADE);内消旋-5,5,7,12,12,14-六甲基-1,4,8,11-四氮杂环十四烷-N,N＇-二乙酸(TETADA);内消旋-5,5,7,12,12,14-六甲基-1,4,8,11-四氮杂环十四烷-N,N＇,N＇,N＇＇＇-四乙酸(TETATA)和内消旋-5,5,7,12,12,14-六甲基-1,4,8,11-四氮杂环十四烷-N,N＇-二异羟肟酸(TETAD-HA).均通过元素分析、IR,1H
NMR和MS表征.
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| 关 键 词： | 大环 配体 氮杂大环 合成 表征 |
Synthesis and Characterization of New N-functionalized Macrocyclic Ligands |
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| Abstract.Synthesis and Characterization of New N-functionalized Macrocyclic Ligands[J].Chinese Journal of Synthetic Chemistry,2001,9(3):223-226. |
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| Authors: | Abstract |
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| Abstract: | A series of new N-functionalized tetraazamacrocyclic ligands, C-messo- 5,5,7,12,12,14-hexamethyl- 1,4,8,11- tetraazacyclotetradecane- N, N＇ - bis (ethyl acetate ), C- messo- 5,5,7, 12, 12,14-hexamethyl-1,4,8, 11- tetraazacyclotetradecane- N, N＇, N＇＇, N＇＇＇- tetrakis ( ethyl acetate ),C-messo-5,5,7,12,12, 14- hexamethyl- 1,4, 8, 11- tetraaazacyclotetradecane- N, N＇- diacetic acid,C-messo-5, 5, 7, 12, 12, 14-hexamethyl-1, 4, 8, 11-tetraazacyclotetradecane-N, N＇, N", N＇＇＇-tetraacetic acid and C-messo-5,5,7, 12, 12,14- hexamethyl- 1,4,8, 11- tetraazacyclotetradecane- N,N＇-dihydroxamic acid(TETADHA) have been synthesized and characterized by elemental analysis,IR, 1H NMR and MS. |
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| Keywords: | mocrocyclic ligand nitrogen heterocyclic ring synthesis characterization |
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