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Fabrication and Characterization of Ultrathin Graphene Oxide/Poly(Vinyl Alcohol) Composite Films via Layer-by-Layer Assembly
Authors:Xiaoyan Wang  Tianxi Liu
Institution:Key Laboratory of Molecular Engineering of Polymers of Ministry of Education, Department of Macromolecular Science, Laboratory of Advanced Materials , Fudan University , Shanghai , P. R. China
Abstract:Novel multilayer ultrathin films comprised of graphene oxide (GO) and poly(vinyl alcohol) (PVA) were fabricated through a layer-by-layer (LBL) assembly technique. GO could self-assemble onto quartz substrates alternately with PVA via hydrogen-bonding interactions. X-ray diffraction, atomic force microscopy, and transmission electron microscopy analysis revealed that GO was exfoliated to monolayers. The ultrathin films, with PVA/GO multilayer structures fabricated by LBL assembly, were characterized by ultraviolet-visible spectroscopy and X-ray diffraction analysis, confirming that the assembly of the multilayer films was quantitative and reproducible.
Keywords:graphene oxide  hydrogen bonding  layer-by-layer assembly  poly(vinyl alcohol)
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