| Hydrothermal Synthesis and Crystal Structure of a Cadmium（Ⅱ） Polymer with One-dimensional Chain Structure： [Cd（MDPPz）（BDC）（H2O）]n |
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| 引用本文： | 李传碧,周实,李秀梅,刘博.Hydrothermal Synthesis and Crystal Structure of a Cadmium（Ⅱ） Polymer with One-dimensional Chain Structure： [Cd（MDPPz）（BDC）（H2O）]n[J].结构化学,2007,26(11):1349-1352. |
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| 作者姓名： | 李传碧 周实 李秀梅 刘博 |
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| 作者单位： | Department of Chemistry Jilin Normal University，Department of Chemistry，Jilin Normal University，Department of Chemistry，Tonghua Teachers College，Department of Chemistry，Jilin Normal University，Siping，Jilin 136000，China，Siping，Jilin 136000，China，Tonghua，Jilin 134002，China，Siping，Jilin 136000，China |
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| 基金项目： | the Natural Science Foundation of Jilin Province (No. 2005103) |
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| 摘 要： | A metal-organic coordination compound formulated as Cd(MDPPz)(BDC)(H2O)]n 1 (MDPPz=11-methyldipyrido3,2-a:2',3'-c]phenazine,BDC=1,4-benzenedicarboxylate) has been hydrothermally synthesized and structurally characterized by elemental analysis,IR spectrum,fluorescence spectrum and single-crystal X-ray diffraction. The title compound crystallizes in the monoclinic system,space group C2/c,with a=30.673(8),b=9.623(3),c=20.784(6) ,β=98.646(3)o,V=6065(3)3,C27H17CdN4O5,Mr=589.85,Dc=1.292 g/cm3,μ(MoKα)=0.757 mm-1,F(000)=2360,Z=8,the final R=0.0381 and wR=0.0855 for 4191 observed reflections (I>2σ(I)). 1 exhibits blue fluorescence property at room temperature.
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| 关 键 词： | 镉混合物 晶体结构 荧光 化学结构 |
| 收稿时间： | 2007-07-28 |
| 修稿时间： | 2007-09-23 |
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