| 催化新材料——钛硅分子筛合成及应用研究* |
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| 引用本文： | 周继承,王祥生.催化新材料——钛硅分子筛合成及应用研究*[J].化学进展,1998,10(4):381-394. |
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| 作者姓名： | 周继承 王祥生 |
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| 作者单位： | 大连理工大学碳资源综合利用开放实验室 大连 116012 |
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| 基金项目： | 中国科学院资助项目，中国石油化工总公司资助项目，，，， |
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| 摘 要： | 评述了钛硅分子筛新催化材料的合成及其催化应用的研究进展, 包括钛硅分子筛(TS21) 的水热合成方法、原料、模板剂、影响因素、TS21 同晶取代法合成、表征、活性中心、钛硅分子筛双氧水体系的应用研究及近年中孔钛硅分子筛的进展。对未来的研究提出了建议。
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| 关 键 词： | 钛硅 苯酚羟基化 环氧化 催化氧化 双氧水 分子筛 |
| 收稿时间： | 1997-08-01 |
| 修稿时间： | 1998-03-01 |
The Syntheses and Applications of Titanium Silicalite Molecular Sieves as a New Kind of Catalytic Materials |
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| Zhou Jicheng,Wang Xiangsheng.The Syntheses and Applications of Titanium Silicalite Molecular Sieves as a New Kind of Catalytic Materials[J].Progress in Chemistry,1998,10(4):381-394. |
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| Authors: | Zhou Jicheng Wang Xiangsheng |
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| Institution: | Open Laboratory of Comprehensive Utilization for Carbon Resources,Dalian University of Technology, Dalian 116012, China |
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| Abstract: | Recent developments in the applications and syntheses of titanium silicalite molecular sieves as a new kind of catalytic materials were reviewed, including developments of TS 1 hydrothermal synthesis methods, raw materials, templating agents, affecting factors, TS 1 synthesis by isomorphous replacement, charaterization, active sites, applications of titanium silicalite catalytic oxidation system using hydrogen peroxide, and research of mesoporous titanium silicalite molecular sieves. Suggestions for further research were proposed. |
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| Keywords: | titanium silicalite hydroxylation of phenol epoxidation catalytic oxidation hydrogen peroxide molecular sieves |
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