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Infrared and Raman study of some chloroparabenzoquinone,derivatives
Affiliation:1. Study Programme of Cosmetic Engineering, Institut Teknologi Sumatera, South Lampung 35365, Indonesia;2. Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Indonesia, Depok 16424, Indonesia;3. Research Center for Chemistry, National Research and Innovation Agency (BRIN), B.J. Habibie Science and Technology Area, South Tanggerang 15314, Indonesia;4. Study Programme of Pharmacy, Department of Sciences, Institut Teknologi Sumatera, South Lampung 35365, Indonesia;1. Eindhoven University of Technology, P.O. Box 513, 5600 MB, Eindhoven, the Netherlands;2. Nobian, P.O. Box 2089, 3800 CB, Amersfoort, the Netherlands;1. Department of Chemistry, The University of Texas at Austin, Austin, Texas, USA;2. Merck Research Laboratories, Merck & Co, Inc, South San Francisco, California, USA;3. Department of Surgery, Baylor College of Medicine, Houston, Texas, USA;1. Istanbul University-Cerrahpasa, Engineering Faculty, Department of Chemistry, Division of Organic Chemistry, Avcilar 34320, Istanbul, Turkey;2. Marmara University, Engineering Faculty, Department of Chemical Engineering, 34722 Goztepe, Istanbul, Turkey
Abstract:The infrared and Raman spectra of some chloroquinones have been obtained and compared with the spectrum of para benzoquinone. Vapour, solution and crystal phase data are presented. The complete vibrational assignment of p-benzoquinone has been made [1], and this has been used to aid the assignment of the chloro derivatives. The 2,5 dichloro derivative is considered in some detail and the results for the 2,6 and the tetra-chloro compounds are briefly summarised. The bonding within these structures is discussed.
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