Poly(urethane‐co‐benzoxazine)s via reaction of phenol terminated urethane prepolymers and benzoxazine monomer and investigation of their properties |
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Authors: | Sadegh Jamshidi Hamid Yeganeh Shahram Mehdipour‐Ataei |
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Institution: | Polyurethane Department, Iran Polymer and Petrochemical Institute, PO Box 14965/115, Tehran, Iran |
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Abstract: | In the present work, a new method was developed for the combination of polyurethanes (PUs) and polybenzoxazine (PBz) to obtain novel thermoset poly(urethane‐co‐benzoxazine)s with good thermal, mechanical, and electrical properties as well as low temperature curing profile. Knowing the catalytic effect of compounds possessing free phenolic groups on ring opening polymerization of benzoxazine monomers, preparation of phenol terminated urethane oligomers (PTPU) as the macroinitiator for a benzoxazine monomer (Ba) was considered. Firstly, NCO‐terminated urethane prepolymers were prepared from the reaction of poly(tetramethyleneether glycol), and 2,4‐tolylene diisocyanate, and then end functionalized with bisphenol‐A under proper condition. DSC, DMTA, and gel content measurements were applied to find optimum ring opening polymerization condition (170°C for 1 hr and 200°C for 15 min). Various kinds of thermoset polymers were prepared by the reaction of PTPU at different molecular weights with variable contents of Ba. All of monomeric and polymeric materials were characterized by conventional spectroscopic methods and their thermal, mechanical, viscoelastic, and electrical properties were measured and properties were correlated to their structure. Due to the interesting properties of these new materials, the possibility of using them as electrical insulators with higher service temperature in comparison to common PUs were examined and their potential applicability was confirmed. Copyright © 2010 John Wiley & Sons, Ltd. |
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Keywords: | polyurethane polybenzoxazine poly(urethane‐co‐benzoxazine) thermal stability electrical insulation |
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