Polyurea nanocapsules obtained from nano‐emulsions prepared by the phase inversion temperature method

We describe here a new and simple method for preparation of polyurea nanocapsules from nanodroplets that were obtained by the phase inversion temperature (PIT) method. In the first stage, a nano‐emulsion was prepared, by a heating–cooling cycle, in which the oil phase contained an oil soluble monomer (toluene 2 , 4 ‐diisocyanate (TDI)). In the second stage, a water‐soluble monomer and crosslinker (diethylenetriamine (DETA)) was added, leading to formation of a polymeric shell by an interfacial polycondensation reaction. The new method was demonstrated for obtaining nanocapsules of about 100 nm, in which hexadecane, dodecane, or decane were the core materials, without using any special equipment. The morphology and structure of the nanocapsules were evaluated by attenuated total reflection Fourier transform infrared (ATR‐FTIR) measurements and electron microscopy. The thermal behavior of the nanocapsules containing hexadecane was studied by Differential Scanning Calorimetry (DSC) measurements, indicating that such nanocapsules can be utilized in thermal energy storage. Copyright © 2010 John Wiley & Sons, Ltd.