Generation of a carbene-stabilized bora-borylene and its insertion into a C-H bond |
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| Authors: | Bissinger Philipp Braunschweig Holger Damme Alexander Dewhurst Rian D Kupfer Thomas Radacki Krzysztof Wagner Katharina |
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| Affiliation: | Institut für Anorganische Chemie, Julius-Maximilians-Universit?t Würzburg, Am Hubland, 97074 Würzburg, Germany. |
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| Abstract: | A novel NHC adduct of a dihalodiborane(4), 1, is reduced by KC(8) with formation of the five-membered boracycle 2. The reaction most likely proceeds via C-H insertion of an intermediate NHC-stabilized free bora-borylene species. |
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