Enantioselective Addition of Allylic Trimethoxysilanes to Aldehydes Catalyzed by p-Tol-BINAP small middle dotAgF |
| |
| Authors: | Yanagisawa Kageyama Nakatsuka Asakawa Matsumoto Yamamoto |
| |
| Affiliation: | Graduate School of Engineering, Nagoya University, CREST, Japan Science and Technology Corporation (JST), Chikusa, Nagoya 464-8603 (Japan). |
| |
| Abstract: | ![]()
Catalytic asymmetric allylation of aldehydes with allylic trimethoxysilanes was achieved with the p-Tol-BINAP small middle dotAgF complex as catalyst [Eq. (a); p-Tol-BINAP=2,2'-bis(di-p-tolylphosphanyl)-1,1'-binaphthyl)]. High anti and enantioselectivities were obtained in the reaction with crotyltrimethoxysilane, irrespective of the configuration at the double bond. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
