Mechanism of the oxidation of cycloheptanone by chloramine-T |
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Authors: | Adarsh Kumar A. K. Bose Prof. S. P. Mushran |
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Affiliation: | (1) Department of Chemistry, University of Allahabad, 211002 Allahabad, India |
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Abstract: | The oxidation kinetics of cycloheptanone by chloramine-T in alkaline media has been investigated. A mechanism involving the formation of an intermediate by the interaction between the enolic anion of cycloheptanone and chloramine-T in a slow step followed by its interaction with another molecule of chloramine-T in a fast step leading to products has been proposed. The scheme satisfactorily accords with the observed stoichiometry, negligible influence of ionic strength and a positive dielectric effect. Various rate parameters have been computed and 1.2-cycloheptanedione identified as the end product.With 2 Figures |
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