|
|||||
|
|
The Coordination and Transformation of Arene Rings by Transition Metal Carbonyl Cluster Complexes |
|
| Authors: | Sabrina Brait Stefano Deabate Selby A. R. Knox Enrico Sappa |
| Affiliation: | (1) Dipartimento di Chimica IFM, Università di Torino, Via Pietro Giuria 7, I-10125 Torino, Italy;(2) School of Chemistry, University of Bristol, Bristol BS8 1TS, U.K;(3) Dipartimento di Scienze e Tecnologie Avanzate, Università del Piemonte Orientale Amedeo Avogadro, Corso Borsalino 54, 15100 Alessandria, Italy |
| Abstract: | A survey of the synthetic pathways and of the reactivity and catalytic activity of transition metal carbonyl clusters substituted with benzyne (and, for comparison, benzene and diene) ligands is given. Cluster-surface analogies are helpful in gaining an understanding of the homogeneous and heterogeneous catalytic behaviour of the clusters. |
| Keywords: | transition metal clusters benzyne ligands reactivity cluster-surface analogy hydrogenation catalysis (homogeneous, solid-gas, heterogeneous) |
| 本文献已被 SpringerLink 等数据库收录！ | |